| Father | Johann Ernst von Nassau-Weilburg Count of Nassau-Weilburg (1664 - 1719) |
| Mother | Maria Polyxena von Leiningen-Dagsburg-Hartenburg Countess Leiningen-Dagsburg-Hartenburg (1662 - 1725) |
| Sibling | Karl August von Nassaui-Weilburg Prince von Nassaui-Weilburg (1685 - 1753) |
| Sibling | Magdalene Henriette von Nassau-Weilburg Gräfin von Nassau-Weilburg (1691 - 1725) |
| Sibling | Heinrich Ludwig Prince Of Nassau (1690 - 1691) |
| Sibling | Karl August Prince of Nassaui-Weilburg Weilburg (1685 - 1753) |
| Sibling | Albertina Christiane Luise, Princess of Nassau- Weilburg (1693 - 1748) |
| Sibling | Johanna Luise, Princess of Nassau- Weilburg (1687 - 1688) |
| Sibling | Totgeburt Nassau (1694 - 1694) |
| Sibling | Marie Polyxena, Princess of Nassau- Weilburg (1686 - 1687) |
| Sibling | Friedrich Ludwig Prince Of Nassau (1683 - 1703) |